https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 Plasmon responses in the sodium tungsten bronzes https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:32917 x WO3) are vividly coloured metallic materials where the optical behaviour can be attributed to the bulk plasma frequency occurring in the visible part of the spectrum. A combination of density functional theory (DFT) calculations and experimental electron energy-loss spectroscopy (EELS) was used to assess their bulk and surface plasmon responses. It was observed that Nax WO3 can sustain strong localised surface plasmon resonances (LSPR) with an energy that can be tuned by changing the Na content. They have a stronger plasmonic response when compared to Au and do not suffer from the atmospheric corrosion of Ag, giving them good potential for plasmonic applications]]> Wed 02 Jun 2021 20:44:08 AEST ]]> Plasmonic enhancement of aqueous processed organic photovoltaics https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:43928 xWO3) is a promising alternative plasmonic material to nanoparticulate gold due to its strong plasmonic resonances in both the visible and near-infrared (NIR) regions. Additional benefits include its simple production either as a bulk or a nanoparticle material at a relatively low cost. In this work, plasmonic NaxWO3 nanoparticles were introduced and mixed into the nanoparticulate zinc oxide electron transport layer of a water processed poly(3-hexylthiophene):phenyl-C61-butyric acid methyl ester (P3HT:PC61BM) nanoparticle (NP) based organic photovoltaic device (NP-OPV). The power conversion efficiency of NP-OPV devices with NaxWO3NPs added was found to improve by around 35% compared to the control devices, attributed to improved light absorption, resulting in an enhanced short circuit current and fill factor.]]> Mon 29 Jan 2024 18:51:02 AEDT ]]>